论文发表

                           

 分类:   Independent Work      Prior to DHU

 年份:   2021  2020  2019   2018    2017    2015    2014    2013    2012    2010    2009



Independent Work


2021


32. “Selective Fluoromethyl Couplings of Alkynes via Nickel Catalysis”

Li, H.; Wang, F.; Zhu, S.; Chu, L.* Angew. Chem. Int. Ed. 2021, DOI: 10.1002/anie.202116725


31. “Selective Ni-catalyzed cross-electrophile coupling of alkynes, fluoroalkyl halides, and vinyl halides”
Dai, Y.; Wang, F.; Zhu, S.; Chu, L.* Chin. Chem. Lett. DOI: 10.1016/j.cclet.2021.12.050.

 # Special issue for Fluorine Chemistry


30. “Divergent Aminocarbonylations of Alkynes Enabled by Photoredox/Nickel Dual Catalysis”
Zhao, X.; Feng, X.; Chen, F.; Zhu, S.; Qing, F.-L.; Chu, L.* Angew. Chem. Int. Ed. 2021, 60, 26511-26517.image


29. “Recent Advances in Photoredox/Nickel Dual-Catalyzed Difunctionalization of Alkenes and Alkynes”
Xu, L.; Wang, F.; Chen, F.; Zhu, S.; Chu, L.* Chin. J. Org. Chem. 2021, 41, DOI: 10.6023/cjoc202109002.

# Invited review



28.  “Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel”
Zhu, S,-Q.; Zhao, X.; Li, H.; Chu, L.* Chem. Soc. Rev., 2021, 50, 10836-10856.

Graphical abstract:Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel


27. “Ni-Catalyzed Ligand-Controlled Regiodivergent Reductive Dicarbofunctionalization of Alkenes”


Li, X.; Chu, L.* Chin. J. Org. Chem. 2021, 41, 4101-4102.  DOI: 10.6023/cjoc202100076.

# Invited Highlight





26. “Reductive hydrobenzylation of terminal alkynes via photoredox and nickel dual catalysis”
Zhao, X.; Zhu, S,-Q.; Qing, F.-L.; Chu, L.* Chem. Commun., 2021, 57, 9414-9417.
Graphical abstract:Reductive hydrobenzylation of terminal alkynes via photoredox and nickel dual catalysis
25. “Radical 1,2-addition of bromoarenes to alkynes via dual photoredox and nickel catalysis”
Xu, L.#; Zhu, S,-Q.; Huo, L,-P.; Chen, F.; Yu, W.; Chu, L.* Org. Chem. Front., 2021, 8, 2924-2931.

Graphical abstract:Radical 1,2-addition of bromoarenes to alkynes via dual photoredox and nickel catalysis

24. “Photoinduced triiodide-mediated [3+2] cycloaddition of N-tosyl aziridines and alkenes”

Li, Y,-B.#; Chen, F.: Zhu, S,-Q.; Chu, L.* Org. Chem. Front., 2021, 8, 2196-2202.


Graphical abstract:Photoinduced triiodide-mediated [3 + 2] cycloaddition of N-tosyl aziridines and alkenes


23. “Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates”

Qin, J.; Zhu, S,-Q.; Chu, L.* Organometallics., 2021, 40, 2246-2252.


22. “Borates as a Traceless Activation Group for Intermolecular Alkylarylation of Ethylene through Photoredox/Nickel Dual Catalysis”

Feng, X.-L.; Guo, L.; Zhu, S.-Q.; Chu, L.* Synlett., 2021, 32, 1519-1524.




21. “Silver‐Enabled General Radical Difluoromethylation Reaction with TMSCF2H”

Yang, J.#; Zhu, S,-Q.; Wang, F.; Qing, F.-L.; Chu, L.* Angew. Chem. Int. Ed., 2021, 60, 4300-4306.


image



20. “Organic-photoredox-catalyzed three-component sulfonylative pyridylation of styrenes”
Wang, F.; Qin, J.; Zhu, S.; Chu, L.* RSC Adv. 2021, 11, 142-146.



2020

19. “Cu-Catalyzed Regio-and Stereo-selective 1,3-and 1,4-Diborylations of CF3-Containing 1,3-Enynes”

Zhu, S.; Chu, L.* Chin. J. Org. Chem. 2020, 40, 3980-3981.

# Invited Highlight




18. “General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis”

Guo, L.#; Yuan, M.-B.#; Zhang, Y.-Y.; Wang, F.; Zhu, S.-Q.; Osvaldo Gutierrez*; Chu, L.*

J. Am. Chem. Soc., 2020, 142, 20390.



17. “Enantioselective Three-Component Fluoroalkylarylation of UnactivatedOlefins Through Nickel-Catalyzed Cross-Electrophile Coupling”

Tu, H.-Y.#; Wang, F.#; Huo, L.-P.; Li, Y.-B.; Zhu, S.-Q.; Zhao, X.; Li, H.; Qing, F.-L.; Chu, L.*

J. Am. Chem. Soc., 2020,142, 9604.


Abstract Image



16. “Sequential C-O Decarboxylative Vinylation/C-H Arylation of Cyclic Oxalates via Nickel-Catalyzed Multicomponent Radical Cascade”

Li, H.#; Guo, L.#; Feng, X.-L.; Huo, L.-P.; Zhu, S.-Q.; Chu, L.* Chem. Sci., 2020,11, 4904.


Graphical abstract:Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

 

15.  “Recent advances in photoredox and nickel dual-catalyzed cascade reactions: pushing theboundaries of complexity”

Zhu, C.; Yue, H.-F.; Chu, L.; Rueping, M. Chem. Sci., 2020,11, 4051-4064.


Graphical abstract:Recent advances in photoredox and nickel dual-catalyzed cascade reactions:pushing the boundaries of complexity


14.“Recent Advances in Nickel-Catalyzed Three-Component Difunctionalization of Unactivated Alkenes”

Tu, H.-Y.; Zhu, S.-Q.*;Qing, F.-L.; Chu, L.*, Synthesis., 2020,52, 1346-1356.

 


2019



13. “Visible‐Light‐Enabled Stereodivergent Synthesis of (E)‐ and (Z)‐1,4‐Dienes via Photoredox/Nickel Dual Catalysis**”

Song, F.; Wang, F.; Guo, L.; Feng, X.-L.; Zhang, Y.-Y.; Chu, L.*, Angew.Chem.Int.Ed., 2019,59, 177-181.


image

 

12. “Bisphosphonium salt: an effective photocatalyst for the intramolecular hydroalkoxylation of olefins”

Cheng, H.; Wang, X.; Chang, L.; Chen, Y.-L.; Chu, L.*; Zuo, Z.-W.*, Sci. Bull., 2019,64, 1896-1901.


11. 'Selective, Intermolecular Alkylarylation of Alkenes via Photoredox/Nickel Dual Catalysis”

Guo, L.#; Tu, H.-Y.#; Zhu, S.-Q.; Chu, L.*, Org. Lett., 2019, 21, 4771-4776.


Abstract Image


10. “Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine”

Zhu, S.-Q.; Qin, J.; Wang, F.; Li, H.; Chu, L.*, Nat. Commun., 2019,10, 749



9. “Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis”

Chen, J.#; Zhu, S.-Q.#; Qin, J.; Chu, L.*, Chem. Commun., 2019,55, 2336-2339.






2018



8. “Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis”

Xu, L.; Chen, J.; Chu, L.*, Org. Chem. Front.,2018, 6, 512-516.


Graphical abstract:Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis


7. “A four-component radical cascade trifluoromethylation reaction of alkenes enabled by an electron-donor–   acceptor complex”

Tu, H.-Y.; Zhu, S.-Q.; Qing, F.-L.; Chu, L.*, Chem. Commun. 2018, 54, 12710-12713.       

 

Graphical abstract:A four-component radical cascade trifluoromethylation reaction of alkenes enabled by an electron-donor–acceptor complex


6. “Metal-free, intermolecular carbopyridylation of alkenes via visible-light-induced reductive radical coupling”

Chen, D.; Xu, L.; Long, T.; Zhu, S.-Q.; Yang, J.; Chu, L.*, Chem. Sci., 2018, 9,  9012-9017.


Graphical abstract:Metal-free, intermolecular carbopyridylation of alkenes via visible-light-induced reductive radical coupling



5. “syn-Selective Alkylarylation of Terminal Alkynes via the Combination of Photoredox and Nickel Catalysis”

Guo, L.; Song, F.; Zhu, S.-Q.; Li, H.; Chu, L.*, Nat. Commun., 2018, 9, 4543.



4. “Ligand-Accelerated, Branch-Selective Oxidative Cyanation of Alkenes”

Yang, J.; Li, H.; Qin, J.; Song, F.; Zhang, J.; Qing, F.-L.; Chu, L.*, Sci. Bull., 2018, 63, 1479.



3. “Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay”

Zhao, X.#; Tu, H.-Y.#; Guo, L.; Zhu, S.-Q.; Qing F.-L.; Chu, L.*, Nat. Commun., 2018, 9, 3488.



X-MOL 评论:http://www.x-mol.com/news/14833

东华大学新闻链接:https://mp.weixin.qq.com/s/q6dtfPQiblX9HCqSwbClSA


2. “Catalytic, Metal-free Sulfonylcyanation of Alkenes via Visible light Organophotoredox Catalysis”

 Sun, J.#; Li, P.#; Guo, L.; Yu, F.; He, Y.-P.*; Chu, L.*, Chem. Commun., 2018, 54, 3162-3165.




2017



1. “Visible-light-induced Halogenation of Aliphatic C-H Bonds”,

Tu, H.; Zhu, S.; Qing, F.-L.; Chu, L*,

Tetrahedron Lett. 2017, 59, 173-179. (Invited Review)




Prior to DHU



2015



24. “Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers”

Liu, J.-B.; Chen, C.; Chu, L. Chen, Z.-H.; Xu, X.-H.; Qing, F.-L.*,

Angew. Chem. Int. Ed. 2015, 54, 11839-11842.


23. “Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones via the Decarboxylative Arylation of α-Oxo Acids”,

Chu, L.; Lipshultz, J. M.; MacMillan, D. W. C.*,

Angew. Chem. Int. Ed. 2015, 54, 7929−7933 (Very Important Paper).



2014



22. “Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin”,

Chu, L.; Ohta, C.; Zuo, Z.; MacMillan, D. W. C.*,

J. Am. Chem. Soc. 2014, 136, 10886−10889.


21. “Merging Photoredox with Nickel Catalysis: Coupling of α-Carboxyl sp3-Carbons with Aryl Halides”

Zuo, Z.; Ahneman, D.; Chu, L.; Terrett, J.; Doyle, A. G.*; MacMillan, D.W. C.*,

Science 2014, 345, 437−440.


20. “Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as A Nucleophilic CF3 Source”,

Chu, L.; Qing, F.-L.*,

Acc. Chem. Res. 2014, 47, 1513−1522.



2013



19. “Direct introduction of ethoxycarbonyldifluoromethyl-group to heteroarenes with ethyl bromodifluoroacetate via visible-light photocatalysis”

Lin, Q.; Chu, L.; Qing, F.-L.*,

Chin. J. Chem. 2013, 31, 885-891.


18. “Copper-Mediated Oxidative Difluoromethylenation of Aryl Boronic Acids with a-Silyldifluoromethylphosphonates: A New Method for Aryldifluorophosphonates”

Jiang, X.; Chu, L.; Qing, F.-L.*,

New J. Chem. 2013, 37, 1736−1741.


17. “Total Synthesis of the Trifluoromethylated Analog of Isoaltholactone: 5-Trifluoromethylisoaltholactone”

Chen, J.-L.; Chu, L.; Qing, F.-L.*,

J. Fluorine Chem. 2013, 152, 70−76.


16. “Electrophilic Trifluoromethylthiolation of Allylsilanes with Trifluoromethanesulfanamide”

Liu, J.; Chu, L.; Qing, F.-L.*,

Org. Lett. 2013, 15, 894−897.


15. “Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3”

Wu, X.; Chu, L.; Qing, F.-L.*,

Angew. Chem. Int. Ed., 2013, 52, 2198−2202.


14. “PhI(OAc)2-mediated Oxidative Trifluoromethylation of Arenes with CF3SiMe3 under Metal-free Conditions”

Wu, X.; Chu, L.; Qing, F.-L.*,

Tetrahedron Lett. 2013, 54, 249−251.



2012



13. “Synthesis of γ-Fluoroalkylated Allylic Amines Derivatives via Palladium-catalyzed Overman Rearrangement”

Jiang, X.-Y.; Chu, L.; Wang, R.-W.; Qing, F.-L.*,

Tetrahedron Lett. 2012, 53, 6853−6857.


12. “Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur”

Chen, C.; Chu, L.; Qing, F.-L.*,

J. Am. Chem. Soc. 2012, 134, 12454−12457.


11. “Copper-Mediated Oxidative Cross-Coupling Reaction of Terminal Alkynes with α-Silyldifluoromethylphosphonates: An Efficient Method for α,α-Difluoropropargylphosphonates”

Jiang, X.; Chu, L.; Qing, F.-L.*,

Org. Lett.2012, 14, 2870−2873.


10. “Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation”

Chu, L.; Qing, F.-L.*,

Org. Lett. 2012, 14, 2106−2109.


9. “Copper-Catalyzed Aerobic Oxidative Trifluoromethylation of H-Phosphonates Using Trimethyl(trifluoromethyl)silane”

Chu, L.; Qing, F.-L.*,

Synthesis2012, 44, 1521−1525.


8. “Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Trifluoromethyl)trimethylsilane”

Jiang, X.; Chu, L.; Qing, F.-L.*,

J. Org. Chem.2012, 77, 1251−1257.


7. “Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur”

Chen, C.; Xie, Y. Chu, L.; Wang, R. Zhang, X. Qing, F.-L.*,

Angew. Chem. Int. Ed., 2012, 51, 2492−2495.


6. “Copper-Catalyzed Direct C-H Oxidative Trifluoromethylation of Heteroarenes”

Chu, L.; Qing, F.-L.*,

J. Am. Chem. Soc., 2012, 134, 1298−1304.



2010



5. “Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids”

Chu, L.; Qing, F.-L.*,

Org. Lett., 2010, 12, 5060–5063.


4. “Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3”

Chu, L.; Qing, F.-L.*,

J. Am. Chem. Soc., 2010, 132, 7262−7263.


3. “Benzoyl Peroxide (BPO)-promoted Oxidative Trifluoromethylation of Tertiary Amines with Trimethyl(trifluoromethyl)silane”

Chu, L.; Qing, F.-L.*,

Chem. Commun., 2010, 46, 6285−6287.


2. “Cu(II)-Mediated Methylthiolation of Aryl C−H Bonds with DMSO”

Chu, L.; Yue, X.; Qing, F.-L.*,

Org. Lett., 2010, 12, 1644−1647.



2009



1. “CuBr-Catalyzed Oxidative Difluoromethylation of Tertiary Amines with Difluoroenol Silyl Ethers”

Chu, L.; Zhang, X.; Qing, F.-L.*,

Org. Lett., 2009, 11, 2197−2200.