储玲玲:Photoinduced triiodide-mediated [3+2] cycloaddition of N-tosyl aziridines and alkenes​
发布人:任振夏  发布时间:2021-06-04   

AbstractA metal-free photoinduced triiodide-mediated [3 + 2] cycloaddition of N-Ts aziridines with alkenes is described herein. This operationally simple protocol utilized bench-stable and inexpensive TBAI as a radical mediator, enabling regioselective access to substituted pyrrolidines with good functional group compatibility. Preliminary mechanistic experiments disclosed that TBAI3, generated in situ from TBAI, promoted the crucial radical ring-opening of N-Ts aziridines.


原文链接:https://pubs.rsc.org/en/content/articlelanding/2021/QO/D1QO00102G#fn1